atomic weight
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What is Atomic Weight?
Atomic weight is the ratio of the average atomic mass of an element (always
taken from some sample source) to 1/12th of the mass of an atom of carbon-12. It
is, more or less, a conventional way of referring to the standard atomic weights
published by IUPAC (International Union of Pure and Applied Chemistry).
The following is the equation for the atomic weight of an element:
Al = msample/((1/12)*mcarbon12)
In this equation, Al is atomic weight to be determined, and msample
is the average atomic mass of the element in consideration.
Atomic weight is used commercially and in laboratories in the production of
large amounts of chemical substances. If one wants to know how much of one
compound when reacted with another will produce a quantity of another, one must
first know the atomic weights of the compounds in consideration. In this way,
one will be able to start off with precise amounts of chemicals to be reacted
and will then be able to predict with a degree of certainty the total mass of
the end products of the reaction. Because the atomic weight on an element is in
units of grams/mol, one need only know Avogadro's constant, the amount of
substances to be reacted and their atomic weights.
The atomic weight of an atom can vary regionally due to changing isotopic
composition. Atomic weight is measured by weighing a large number of atoms in a
sample, so the quantity can differ depending on where the sample came from. The
atomic weight of Boron, for example, is different when a sample is from
California as opposed to taking a sample from Turkey. For most practical
purposes this difference is inconsequential, especially when one considers the
high cost of isotope analysis. Most chemists use the published tables of atomic
weights for their calculations.
Atomic weights are known to a high degree of precision for most mononuclidic
elements. Because it is much easier to measure atomic weight for these kinds of
elements, some of them are measured within degrees of precision as high as one
part in 38 million (Fluorine). Isotopic compositions, however, are much more
difficult to get atomic weights for, and therefore are less precise. There is
also more regional variation to be found in isotopic compositions, which makes
it difficult to know that a published number can be substituted for the isotopic
composition of an element being used in a laboratory.
The use of the term "atomic weight" to refer to this particular physical
quantity is has been the subject of controversy since the late 1960s.. Many
have tried to change the name to "relative atomic mass", because the new name
would correlate more directly with the quantity it measures, but there has been
enough support for the conventional term that it remains in use to this day.
Proponents of changing the name argue that atomic weight refers more to a
relative atomic mass than it does the weight of an individual atom (atomic
mass). Proponents of the other view, however, argue that the modern usage of
"atomic weight" has been around for a very long time and that atomic weight
refers to a weighted average.